mer,trans-[Ru(III)Cl3(p-tolylsulfonylmethylisocyanide)2(acetonitrile)] | 285141-43-7

• 英文名称: mer,trans-[Ru(III)Cl3(p-tolylsulfonylmethylisocyanide)2(acetonitrile)]
• CAS: 285141-43-7
• 化学式: C₂₀H₂₁Cl₃N₃O₄RuS₂
• 分子量: 638.965
• InChiKey: RDWRKDSWBIGKSL-UHFFFAOYSA-K

反应信息

• 作为产物：
  描述：

  trans-[ruthenium(III)Cl4(p-tolylsulfonylmethylisocyanide)2](1-) 、 乙腈 以 二氯甲烷 、 乙腈 为溶剂， 生成 mer,trans-[Ru(III)Cl3(p-tolylsulfonylmethylisocyanide)2(acetonitrile)]
  参考文献：
  名称：

  Redox properties of two new ruthenium(III) isocyanide complexes, trans-[NBu4][RuX4(CNTM)2](X=Cl or Br, CNTM=p-tolylsulfonylmethylisocyanide)

  摘要：

  New ruthenium(III) complexes trans-[NBu4][RuX4(CNTM)(2)] (X = Cl or Br, CNTM = p-tolylsulfonylmethylisocyanide) have been prepared by treating [NBu4](2)[RuX6] with the isocyanide ligand CNTM in EtOH-CH2Cl2 solution. In situ IR and UV-Vis spectroelectrochemical studies have shown that reduction of trans-[RuX4(CNTM)(2)](-) in acetonitrile and subsequent oxidation yields mer,trans-[RuX3(CNTM)(2)(NCMe)]. Similar studies have shown, interestingly, that oxidation of trans-[RuX4(CNTM)(2)](-) and subsequent reduction also yields the same product. Differences between the redox behaviour of trans-[RuX4(CNTM)(2)](-) and trans-[RuX4((CNBu)-Bu-t)(2)](-) (X = Cl or Br, (CNBu)-Bu-t = tert-butylisocyanide) in the presence of free isocyanide ligand have also been identified. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(99)00587-3