[η5-1,2,4-(Me3C)3C5H2]Th(SePh)3(2,2'-bipyridine) | 1354564-66-1

• 英文名称: [η5-1,2,4-(Me3C)3C5H2]Th(SePh)3(2,2'-bipyridine)
• 英文别名: [η5-1,2,4-(Me3C)3C5H2]Th(SePh)3(bipy)
• CAS: 1354564-66-1
• 化学式: C₄₅H₅₂N₂Se₃Th
• 分子量: 1089.84
• InChiKey: RYEAOKSHILKIIG-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  二苯基二硒醚 、 [η⁵-1,2,4-(Me₃C)₃C₅H₂]₂Th(bipy) 以 氘代苯 为溶剂， 生成 [η5-1,2,4-(Me3C)3C5H2]Th(SePh)3(2,2'-bipyridine) 、 [η5-1,2,4-(Me3C)3C5H2]3Th(SePh)
  参考文献：
  名称：

  Synthesis, Structure, and Reactivity of a Thorium Metallocene Containing a 2,2′-Bipyridyl Ligand

  摘要：

  The reduction of [eta(5)-1,2,4-(Me3C)(3)C5H2](2)ThCl2 (1) with potassium graphite in the presence of 2,2'-bipyridine gives the purple thorium bipy metallocene [eta(5)-1,2,4-(Me3C)(3)C5H2](2)Th(bipy) (2) in good yield. Complex 2 has been characterized by various spectroscopic techniques, elemental analysis, and single-crystal X-ray diffraction. Complex 2 is a good synthon for low-valent thorium, as shown by the reactivity with silver halides, trityl chloride, pyridine-N-oxide, RN3, 9-diazofluorene, and diphenyl diselenide, yielding the halide metallocenes [eta(3)-1,2,4-(Me3C)(3)C5H2](2)ThX2 (X = Cl (1), F (3), Br (4)), oxo metallocene [eta(3)-1,2,4-(Me3C)(3)C5H2](2)ThO(py) (5), imido metallocenes (Me3C)(3)C5H2](2)Th=NR (R = p-tolyl (6), Ph3C (7), Me3Si (8), (9-C13H8)=N (9)), and selenido complex [eta(3-)1.2.4-(Me3C)(3)C5H2]Th(SePh)(3)(bipy) (10a), in quantitative conversions.

  DOI：

  10.1021/om201015f