| 244764-93-0

• CAS: 244764-93-0
• 化学式: C₄₃H₄₈N₉O₃PRu
• 分子量: 870.956
• InChiKey: XPALAOPKRZOQKN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  Ru(2,2'-bipyridine)2(4-methyl-4'-ethanolamide-bipyridine)bis(hexafluorophosphate) 、 chloro-(2-cyanoethyl)-diisopropylaminophosphane 在 N,N-二异丙基乙胺 作用下， 以 乙腈 为溶剂， 生成
  参考文献：
  名称：

  Automated Solid-Phase DNA Synthesis and Photophysical Properties of Oligonucleotides Labeled at the 5‘-Terminus with Ru(bpy)₃²⁺

  摘要：

  A facile procedure for the incorporation of Ru(bpy)(3)(2+) in an oligonucleotide is reported. A Ru(bpy)(3)(2+) phosphoramidite is synthesized, and then attached to the 5'-terminus of DNA using a standard protocol on an automated DNA solid-phase synthesizer. Photophysical studies of the Ru(II) tris-diimine complex as well as the corresponding labeled oligonucleotides demonstrate that the excited-state electron is localized on one specific bipyridine with the dipole directed toward the linkage to DNA, and that the Ru(II) excited state is long-lived when attached to the DNA.

  DOI：

  10.1021/ic990177y