trans,trans,trans-[ruthenium(II)Cl2(NCPh)2(tert-butylisocyanide)2] | 286960-59-6

• 英文名称: trans,trans,trans-[ruthenium(II)Cl2(NCPh)2(tert-butylisocyanide)2]
• CAS: 286960-59-6
• 化学式: C₂₄H₂₈Cl₂N₄Ru
• 分子量: 544.489
• InChiKey: MBTPCEYDFAPJJE-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  mer-[RuCl3(NCPh)3] 、 异氰酸叔丁酯 以 乙醇 、 二氯甲烷 为溶剂， 以78%的产率得到trans,trans,trans-[ruthenium(II)Cl2(NCPh)2(tert-butylisocyanide)2]
  参考文献：
  名称：

  Spectroelectrochemical studies on some new ruthenium(II) complexes containing both cyanide and isocyanide ligands

  摘要：

  New ruthenium(II) complexes trans, trans, trans-[RuCl(2)(NCR)(2)(CNR')(2)] (R = Me or Ph, R' = Bu', xylyl or cyclohexyl (cy)) have been prepared by treating mer-[RuCl(3)(NCR)(3)] with the appropriate isocyanide ligand CNR' in EtOH/CH(2)Cl(2). These complexes have been shown to be oxidisable electrochemically in situ to the analogous ruthenium(III) species trans, trans, trans[RuCl(2)(NCR)(2)(CNR')(2)](+) in 0.5 mol dm(-3) [NBu(4)(n)][PF(6)]/CH(2)Cl(2) solution, the stereochemistry of the oxidised species being established by use of an infrared spectroelectrochemical (IRRAS) technique. The electronic absorption spectra of the ruthenium(III) species obtained by use of an OTTLE cell are also reported and discussed. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(99)00581-2