[Ru(η,μ-(6-methylopyridin-2-olate))(CO)2(μ3-(6-methylpyridin-2-olate))(CO)2]2 | 861884-29-9

• 英文名称: [Ru(η,μ-(6-methylopyridin-2-olate))(CO)2(μ3-(6-methylpyridin-2-olate))(CO)2]2
• CAS: 861884-29-9
• 化学式: C₃₂H₂₄N₄O₁₂Ru₄
• 分子量: 1060.84
• InChiKey: YKGRJUSUBGUVKE-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2-羟基-6-甲基吡啶 、 以 甲苯 为溶剂， 以66%的产率得到[Ru(η,μ-(6-methylopyridin-2-olate))(CO)2(μ3-(6-methylpyridin-2-olate))(CO)2]2
  参考文献：
  名称：

  New ruthenium complexes from Ru3(CO)12 and 6-Alkyl- or 6-Phenyl-2-hydroxypyridines

  摘要：

  Trirutheniumdodecacarbonyl (RU3(CO)(12)) reacts with 2-hydroxy-6-methylpyridine and with 2-hydroxy-5,6,7,8-tetrahydroquinoline in toluene to form centrosymmetric tetranuclear complexes of the type [Ru(eta(2), mu-L)(CO)(2)(mu(3)-L)Ru(CO)(2)](2), where L is the respective (N,O)-pyridonate ligand (2 and 3). The structures of these complexes, which are almost insoluble in all common solvents, could be determined by single-crystal X-ray diffraction. Reaction of Ru-3(CO)(12) with 2-hydroxy-4,6-diphenylpyridine in methanol includes ortho-metallation at the phenyl ring, furnishing the dinuclear complex [Ru(kappa(2)N, C-L)(CO)(2)(mu-OCH3)(2)Ru(CO)(2) (kappa 2N, C-L)] (4), where L = (2-(6-hydroxy-4-phenylpyridin-2-yl)phenyl), according to an X-ray crystal structure determination. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.04.005