[Zn(4'-phenyl-4,2':6',4''-terpyridine)Cl2]n | 857283-22-8

• 英文名称: [Zn(4'-phenyl-4,2':6',4''-terpyridine)Cl2]n
• CAS: 857283-22-8
• 化学式: C₂₁H₁₅Cl₂N₃Zn
• 分子量: 445.666
• InChiKey: HUVMPGRCELCRHY-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  4'-phenyl-4,2':6',4''-terpyridyl 、 zinc(II) chloride 以 乙醇 为溶剂， 以62%的产率得到[Zn(4'-phenyl-4,2':6',4''-terpyridine)Cl2]n
  参考文献：
  名称：

  A new ligand 4′-phenyl-4,2′:6′,4″-terpyridine and its 1D helical zinc(II) coordination polymer: syntheses, structures and photoluminescent properties

  摘要：

  A new ligand 4'-phenyl-4,2':6',4"-terpyridine (L) and its zinc complex [Zn(L)Cl-2](n) (1) have been prepared and structurally characterized by single-crystal X-ray diffraction. In 1, the ligand L, with three non-planar pyridyl rings, links two zinc ions through two terminal pyridines to construct a 1D helical polymer chain, the intrachain Zn...Zn distance is 13.040 Angstrom. Both L and 1 display strong photoluminescence in the solid state at room temperature. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2004.11.030