bis-((μ(2)-acetato-O,O')-.mu-(N,N'-bis(o-hydroxybenzyl)-1,3-diaminopropane)-(aquo)nickel)nickel | 926692-10-6

• 英文名称: bis-((μ(2)-acetato-O,O')-.mu-(N,N'-bis(o-hydroxybenzyl)-1,3-diaminopropane)-(aquo)nickel)nickel
• 英文别名: ([Ni(H4Salpr)(H2O)]2(OAc)2Ni)
• CAS: 926692-10-6
• 化学式: C₃₈H₅₀N₄Ni₃O₁₀
• 分子量: 898.906
• InChiKey: PGNUWXZWZGSIHM-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  N,N'-bis(2-hydroxybenzyl)-1,3-diaminopropane 、 nickel diacetate 以 甲醇 为溶剂， 以50%的产率得到bis-((μ(2)-acetato-O,O')-.mu-(N,N'-bis(o-hydroxybenzyl)-1,3-diaminopropane)-(aquo)nickel)nickel
  参考文献：
  名称：

  Hydrogenated Schiff base ligands: Towards the controlled organisation of open metal frameworks

  摘要：

  The synthesis and structures of bis-((mu(2)-acetato-O,O')-mu-(N,N'-bis-(o-hydroxybenzyl)-1,3-diaminopropane)-(aquo)nickel)nickel, his((mu(2) -acetato-O,O')-mu-(N,N-bis-(o-hydroxybenzyl)-1,4-diaminobutane nickel)nickel acetate) and bis-((mu(2)-acetato-O,O')-mu-(N,N-bis(o-hydroxybenzyl)-1,4-diaminobutane)-(dimethylformamido)nickel)nickel are reported. These compounds are designed to draw attention to the wider structural catalogue available to symmetrical hydrogenated Schiff base complexes which contain a tetramethylene backbone. (C) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2006.04.013