monohydrochloric acid chlorine | 12015-40-6

• 英文名称: monohydrochloric acid chlorine
• 英文别名: hydrochloric acid chloride；hydrochloric acid chlorine；hydrogen chloride chlorine；dichlorohydrogen
• CAS: 12015-40-6
• 化学式: Cl₂H
• 分子量: 71.9139
• InChiKey: BVEWTXIHOKWUGS-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  hydrochloric acid dimer 以 neat (no solvent) 为溶剂， 生成 monohydrochloric acid chlorine
  参考文献：
  名称：

  Probing the Cl–HCl complex via bond-specific photodissociation of (HCl)2

  摘要：

  Infrared-ultraviolet double resonance has been used to photodissociate the free HCl bond of the HCl dimer. This creates Cl-HCl in a coherent superposition of electronic and vibrational states. Measurement of the translational energy of the departing H atom using high-n Rydberg time-of-flight spectroscopy enables the Cl-HCl potential surfaces to be probed. The features thus obtained agree with theoretical estimates. At long IR-UV delays, the fastest H atoms derive primarily from UV photodissociation of internally excited HCl (e.g., high rotational levels) formed by (HCl)(2) predissociation. (C) 1999 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0009-2614(98)01293-7