[(salicylaldehyde-N,N-diphenyl semicarbazone)aquacopper(II)] | 637748-61-9

• 英文名称: [(salicylaldehyde-N,N-diphenyl semicarbazone)aquacopper(II)]
• CAS: 637748-61-9
• 化学式: C₂₀H₁₇CuN₃O₃
• 分子量: 410.919
• InChiKey: HBMWUZMSGYBSRR-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  copper(II) choride dihydrate 、 salicylaldehyde-N,N-diphenyl semicarbazone 以 甲醇 、 二氯甲烷 为溶剂， 以86%的产率得到[(salicylaldehyde-N,N-diphenyl semicarbazone)aquacopper(II)]
  参考文献：
  名称：

  Synthesis, characterization and physicochemical properties of copper(II) complexes containing salicylaldehyde semicarbazone

  摘要：

  Copper(II) complexes containing a series of salicylaldehyde semicarbazone ligands have been prepared and characterized by a range of physicochemical techniques. The X-ray structure of [Cu(HBnZ(2))Cl] . H2O (5) (where HBnz(2) is salicylaldehyde-N,N-dibenzyl semicarbazone) shows the complex is monomeric and the copper atom is four coordinated in a distorted square planar geometry. The ligand chelates the copper in a tridentate fashion through the imine N, carbonyl O and phenolato O with the fourth position being occupied by coordinated Cl. The compound [Cu(Ph-2) . H2O] (4) (where Ph-2 is salicylaldehyde-N,N-diphenyl semicarbazone) is also formulated as a monomer whereas all other complexes are assumed to have a side-by-side dimeric arrangement of the metal chelating with the phenolate bridging the Cu(II) centres. (C) 2003 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(03)00402-9