| 248938-04-7

• CAS: 248938-04-7
• 化学式: C₂₄BF₂₀*C₄₆H₈₁ClNP₂Ru
• 分子量: 1525.67
• InChiKey: RLXZVHIUGBBEJJ-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  [hydridobis(tricyclohexylphosphane)(vinyldene)chlororuthenium(II)] 、 N,N-二甲基苯铵四(五氟苯基)硼酸盐 以 二氯甲烷-D2 为溶剂， 生成
  参考文献：
  名称：

  Carbynehydridoruthenium Complexes as Catalysts for the Selective, Ring-Opening Metathesis of Cyclopentene with Methyl Acrylate

  摘要：

  The first members of a homologous series of long-chain, multiply unsaturated esters were obtained upon selective ring-opening metathesis of cyclopentene with methyl acrylate [Eq. (a)]. The catalysts are cationic carbynehydridoruthenium complexes (e.g. L=OEt2 ), which were prepared for the first time by protonation of hydridovinylideneruthenium compounds in the presence of L.

  DOI：

  10.1002/(sici)1521-3773(19981231)37:24<3421::aid-anie3421>3.0.co;2-u