[Ru3Fe2(μ(4)-S)(μ(3)-Se)(CO)17] | 306974-50-5

• 英文名称: [Ru3Fe2(μ(4)-S)(μ(3)-Se)(CO)17]
• CAS: 306974-50-5
• 化学式: C₁₇Fe₂O₁₇Ru₃SSe
• 分子量: 1002.11
• InChiKey: IBRXVIMIOXPIGO-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  [Fe2(μ-SSe)(CO)6] 、 十二羰基三钌 以 苯 为溶剂， 以17%的产率得到[Ru3Fe2(μ(4)-S)(μ(3)-Se)(CO)17]
  参考文献：
  名称：

  Synthesis and characterisation of [Fe2M3(μ4-E)(μ3-E′)(CO)17] and [Os3(μ3-E)(μ3-E′)(CO)9] (M=Os or Ru; E=S, Se, Te; E′=Se, Te)

  摘要：

  A set of new chalcogen-bridged mixed metal clusters [Fe2Os3(mu(4)-E)(mu(3)-E')(CO)(17)] (2, EE' = SeTe; 3, EE' = STe; 4, EE' = Se-2; 5 EE' = SSe) and [Fe2Ru3(mu(4)-E)(mu(3)-E')(CO)(17)] (12, EE' = SeTe; 13, EE' = STe; 14, EE' = Se-2; 15, EE' = SSe) has been synthesised by facile methods. Thermolysis or photolysis of compounds 2, 3 and 5 afforded the new triosmium mixed chalcogenide clusters [Os-3(mu(3)-E)(mu(3)-E)(CO)(9)] (7, EE' = SeTe; 8, EE' = STe; 10, EE' = SSe). All new compounds were characterised by IR and H-1-, Se-77- and Te-125-NMR spectroscopy. Clusters 8, 9 and 12 were structurally characterised by single crystal X-ray diffraction methods. (C) 2000 Published by Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(00)00344-2