μ-aqua-1:2κ(2)O-tetrapyridine-1κ(2)N,2κ(2)N-bis(μ-stearato)-1κ(2)O:2κ(2)O'-bis(stearato)-1κ(O),2κO-dicobalt(II) | 192506-49-3

• 英文名称: μ-aqua-1:2κ(2)O-tetrapyridine-1κ(2)N,2κ(2)N-bis(μ-stearato)-1κ(2)O:2κ(2)O'-bis(stearato)-1κ(O),2κO-dicobalt(II)
• CAS: 192506-49-3
• 化学式: C₉₂H₁₆₂Co₂N₄O₉
• 分子量: 1586.31
• InChiKey: LLYFHKQFHUTRHQ-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  吡啶 、 水 、 cobalt(II) stearate 以 吡啶 为溶剂， 生成 μ-aqua-1:2κ(2)O-tetrapyridine-1κ(2)N,2κ(2)N-bis(μ-stearato)-1κ(2)O:2κ(2)O'-bis(stearato)-1κ(O),2κO-dicobalt(II)
  参考文献：
  名称：

  A Water-Bridged Dinuclear Complex of Cobalt(II), Pyridine and Stearic Acid

  摘要：

  In the crystal structure of mu-aqua-1:2 kappa(2)O-tetrapyridine-1 kappa(2)N,2 kappa(2)-N-bis(mu-stearato)- 1 kappa(2)O:2 kappa(2)O'-bis(stearato)-1 kappa O, 2 kappa O-dicobalt (II), [CO2(C18H35O2)(4)(C5H5N)(4)-(H2O), hydrogen bonding [with an O...O distance of 2.564 (5) A] between the H atoms of the bridging water and the non-metal-bonding O atoms of the monodentate stearic acid molecules, stabilizes the dimeric core complex and consequently limits chain packing and conformation options. The structure is a member of a rare class of compounds, the well crystallized metallic salts of long-chain fatty acids. The structure also bears a remarkable similarity to built-up Langmuir-Blodgett films of metal carboxylates.

  DOI：

  10.1107/s010827019700259x