((benzoin thiosemicarbazonato)Pd(II)Cl)2 | 159794-31-7

• 英文名称: ((benzoin thiosemicarbazonato)Pd(II)Cl)2
• CAS: 159794-31-7
• 化学式: C₃₀H₂₈Cl₂N₆O₂Pd₂S₂
• 分子量: 852.469
• InChiKey: XHPHIYJQFHFAKT-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  1-(2-hydroxy-1,2-diphenylethylidene)thiosemicarbazide 、 palladium dichloride 以 乙醇 为溶剂， 生成 ((benzoin thiosemicarbazonato)Pd(II)Cl)2
  参考文献：
  名称：

  Synthesis and spectral studies of platinum metal complexes of benzoin thiosemicarbazone

  摘要：

  The platinum metal chelates of benzoin thiosemicarbazone obtained with Ru(III), Rh(III), Ir(III), Pd(II) and Pt(II) were prepared from their corresponding halide salts. The complexes were characterized by elemental analysis, conductance measurement, IR, Raman, H-1-NMR, C-13-NMR and UV-visible spectra studies. Various ligand field parameters and nephelauxetic parameters were also calculated. The mode of bonding and the geometry of the ligand environment around the metal ion have been discussed in the light of the available data obtained. Complexes of Ru(III), Rh(III) and Ir(III) are six-coordinate octahedral, while Pd(II) and Pt(II) halide complexes are four-coordinated with halides bridging.

  DOI：

  10.1016/0584-8539(93)e0034-t