| 180847-19-2

• CAS: 180847-19-2
• 化学式: C₃₇H₃₁N₃O₄Re*F₆P
• 分子量: 912.842
• InChiKey: BVDGNNYZDYTHNB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  ammonium hexafluorophosphate 、 、 4-<(9-Anthrylmethoxy)methyl>-4'-methyl-2,2'-bipyridine 以 水 、 甲苯 、 乙腈 为溶剂， 生成
  参考文献：
  名称：

  Designed Intramolecular Competition in a Chromophore−Biquencher Complex

  摘要：

  Competitive energy and electron transfer occur following excitation of the chromophore-biquencher [Re-1(MebpyCH(2)OCH(2)An)(CO)(3)(MQ(+))](PF6)(2)(MebpyCH(2)OCH(2)An is 4-[(9-anthrylmethoxy)methyl]-4'-methyl-2,2'-bipyridine; MQ(+) is N-methyl-4,4',-bipyridinium ion). Following excitation with a 392-nm, 4-ns laser pulse in 1,2-dichloroethane (DCE), the initial excited state energy is distributed in a similar to 2:1 ratio between (3)An* and the lower lying Re-II(MQ(.)) metal-to-ligand charge transfer (MLCT) excited state. The appearance of the two states was monitored by transient absorption spectroscopy, which detected the triplet-triplet band for (3)An* at lambda(max) = 420 nm (tau = 35 +/- 2 mu s, k = (2.9 +/- 0.2) x 10(4) s(-1)) and a pi --> pi* band of MQ(.) at 610 nm (tau = 37 +/- 2 ns, k = (2.7 +/- 0.2) x 10(7) s(-)1). These states result from a competitive partitioning in the initial excited state or states. They do not interconvert to any significant degree on the time scale of the shorter lived, higher energy Re-II(MQ*) state.

  DOI：

  10.1021/jp960977j