[(phd)ReO3Cl] | 1207164-80-4

• 英文名称: [(phd)ReO3Cl]
• 英文别名: [(1,10-phenanthroline-5,6-dione)ReO3Cl]
• CAS: 1207164-80-4
• 化学式: C₁₂H₆ClN₂O₅Re
• 分子量: 479.85
• InChiKey: AEICHDCUGCOGBY-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  1,10-邻二氮杂菲-5,6-二酮 、 苯甲酰氯 、 四丁基高铼酸铵 以 乙腈 为溶剂， 生成 [(phd)ReO3Cl]
  参考文献：
  名称：

  Triazacyclohexane (tach) Complexes of High-Valent Rhenium: Syntheses of [(R₃tach)ReO₃]⁺ (R = −CH₃, −CH₂C₆H₅) and Its Substitution Reactions

  摘要：

  N-Alkylated derivatives of 1,3,5-triazacyclohexane (tach) are versatile, facially coordinating ligands. We present the syntheses and full characterization of two new complexes of the [(R(3)tach)ReO3](+) type. In these complexes, the tach ligand is readily substituted by bi- and tridentate ligands; hence, they can be considered as sources of the [ReO3](+) motif for Re-VII complexes.

  DOI：

  10.1021/ic902114p