[Cu3(bis(oxybenzyl)-1,3-diaminopropane)2(CH3OH)2(ClO4)2] | 835605-10-2

• 英文名称: [Cu3(bis(oxybenzyl)-1,3-diaminopropane)2(CH3OH)2(ClO4)2]
• CAS: 835605-10-2
• 化学式: C₃₆H₄₈Cl₂Cu₃N₄O₁₄
• 分子量: 1022.34
• InChiKey: HIORLZAJSAXXKA-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  甲醇 、 N,N'-bis(2-hydroxybenzyl)-1,3-diaminopropane 、 copper(II) perchlorate 以 甲醇 为溶剂， 以62%的产率得到[Cu3(bis(oxybenzyl)-1,3-diaminopropane)2(CH3OH)2(ClO4)2]
  参考文献：
  名称：

  Structure and magnetism of two new linear trinuclear copper(II) clusters obtained from the tetradentate N2O2 ligand bis(2-hydroxybenzyl)-1,3-diaminopropane

  摘要：

  Reaction of bis(2-hydroxybenzyl)-1,3-diaminopropane (H(2)bhbd) with copper(II) perchlorate and copper(II) chloride in methanol, respectively, leads to linear trinuclear clusters, namely [Cu-3(bhbd)(2)(CH3OH)(2)(ClO4)(2)] (1) and [Cu-3(bhbd)(2)Cl-2](CH3OH)(4) (2). These coordination compounds were characterized by X-ray crystallography, UV-Vis, IR and EPR spectroscopy, and magnetic susceptibility measurements. Both complexes have a linear trinuclear array of copper ions bridged by means of phenolato O atoms and separated by a distance of 2.985(4) Angstrom (1) and 2.937(4) Angstrom (2). Strong antiferromagnetic interactions between these adjacent Cu-II ions govern the magnetochemistry of 1 (J = - 303(1) cm(-1)) and 2 (J = -482(3) cm(-1)) resulting in S = 1/2 ground states fully populated below 150 K. A correlation between the interaction parameter J and the angles within the trinuclear clusters is proposed. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2004.07.033