| 163462-31-5

• CAS: 163462-31-5
• 化学式: C₄₈H₈₈Al₄O₁₆
• 分子量: 1029.14
• InChiKey: MFVVACHWZVKUTG-CYSKKNQXSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [(CH3COCHCOCH3)2Al(μ-OCH(CH3)2)2Al(OCH(CH3)2)2] 、 2-乙基-1,3-己二醇 以 苯 为溶剂， 以97%的产率得到
  参考文献：
  名称：

  Synthesis and characterization of some unique heterocyclic derivatives containing aluminium atoms in four- and six-coordination states—I. Bis(acetylacetonato) aluminium(III)-di-μ-isopropoxo-glycolato aluminium

  摘要：

  Some mixed ligand complexes of aluminium of the type [(acac)(2)Al(mu-OPri)(2)Al(O-g-O)](n) have been prepared by the reactions of [Al(OPri)(2)(acac)](2) and glycols (HO-G-OH) in 1 : 1 molar ratio in refluxing benzene (where acac = CH3COCHCOCH3; G=(CH2)(2), CH2CH(CH3), C(CH3)(2)CH2CH(CH3), OH2CH(C2H5)CH(C2H7), (CH2)(4); (CH2)(5), (CH2)(6); n = 1 or 2). These are soluble in common organic solvents and show tetranuclear behaviour in chloroform except [(acac)(2)Al(p-OPri)(2)Al{OC(CH3)(2)CH2CH(CH3)O}], which is dinuclear. These derivatives have been characterized by elemental analysis, IR, H-1, C-13 and Al-27 NMR spectral studies. Two types of aluminium sites, tetrahedral and octahedral, are present in the Al-27 NMR spectra of all these novel heterocyclic derivatives.

  DOI：

  10.1016/0277-5387(94)00308-2