[(η5-Cp)WCl3]2 | 199539-86-1

• 英文名称: [(η5-Cp)WCl3]2
• CAS: 199539-86-1
• 化学式: C₁₀H₁₀Cl₆W₂
• 分子量: 710.607
• InChiKey: VCOPQUNDSOQNMK-UHFFFAOYSA-H

反应信息

• 作为反应物：
  描述：

  [(η5-Cp)WCl3]2 、 1,2-双(二苯基膦)乙烷 以 二氯甲烷 为溶剂， 生成 [(η5-Cp)WCl3(dppe)]
  参考文献：
  名称：

  Preparation of trichloro- and tribromocyclopentadienyltungsten(IV)

  摘要：

  The thermal decarbonylation of (Ring)WX3(CO)(2) in refluxing toluene has led to the preparation of the CO-free compounds [(Ring)WX3](2) [Ring = eta(5)-C5H5 (Cp) and X = Cl (1a) or Br (1b); Ring = eta(5)-C5H4Me (Cp'), X = Cl (2a) or Br (2b); Ring = eta(5)-C5Me5 (Cp*), X = Cl (3)]. The NMR properties of these molecules are consistent with diamagnetism and thereby indicate a different structure from that of the paramagnetic molybdenum analogues. Compounds la and la react with dppe to afford mononuclear 18-electron adducts, (Ring)WCl3(dppe) (Ring = Cp (4) or Cp' (5)). The X-ray structure of 5 shows a pseudo-fac-octahedral geometry with the dppe ligand occupying two equatorial (e.g. cis relative to Cp') coordination sites. The X-ray structure of two by-products of the synthetic processes are also reported, e.g. Cp-3'W3Cl3(mu(2)-Cl)(2)(mu(3)-O) (6) and [Cp*WCl3](2)(mu-O) (7). (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(99)00292-2
• 作为产物：
  描述：

  [(η5-Cp)WCl3(CO)2] 以 甲苯 为溶剂， 以87%的产率得到[(η5-Cp)WCl3]2
  参考文献：
  名称：

  Preparation of trichloro- and tribromocyclopentadienyltungsten(IV)

  摘要：

  The thermal decarbonylation of (Ring)WX3(CO)(2) in refluxing toluene has led to the preparation of the CO-free compounds [(Ring)WX3](2) [Ring = eta(5)-C5H5 (Cp) and X = Cl (1a) or Br (1b); Ring = eta(5)-C5H4Me (Cp'), X = Cl (2a) or Br (2b); Ring = eta(5)-C5Me5 (Cp*), X = Cl (3)]. The NMR properties of these molecules are consistent with diamagnetism and thereby indicate a different structure from that of the paramagnetic molybdenum analogues. Compounds la and la react with dppe to afford mononuclear 18-electron adducts, (Ring)WCl3(dppe) (Ring = Cp (4) or Cp' (5)). The X-ray structure of 5 shows a pseudo-fac-octahedral geometry with the dppe ligand occupying two equatorial (e.g. cis relative to Cp') coordination sites. The X-ray structure of two by-products of the synthetic processes are also reported, e.g. Cp-3'W3Cl3(mu(2)-Cl)(2)(mu(3)-O) (6) and [Cp*WCl3](2)(mu-O) (7). (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(99)00292-2