(Ru(4,4'-dimethyl-2,2'-bipyridine)(CH3CN)3Cl)Cl | 373389-85-6

• 英文名称: (Ru(4,4'-dimethyl-2,2'-bipyridine)(CH3CN)3Cl)Cl
• CAS: 373389-85-6
• 化学式: C₁₈H₂₁ClN₅Ru*Cl
• 分子量: 479.374
• InChiKey: AUKLMKOCUWKVTI-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  ((η6-C6H6)Ru(4,4'-dimethyl-2,2'-bipyridine)Cl)Cl 、 乙腈 以 乙腈 为溶剂， 生成 (Ru(4,4'-dimethyl-2,2'-bipyridine)(CH3CN)2Cl2) 、 (Ru(4,4'-dimethyl-2,2'-bipyridine)(CH3CN)3Cl)Cl
  参考文献：
  名称：

  Convenient Synthesis of Tris-Heteroleptic Ruthenium(II) Polypyridyl Complexes

  摘要：

  A convenient synthesis of tris-heteroleptic polypyridyl [Ru(pp)(pp')(pp ")](2+) complexes is reported (where pp, pp', and pp " represent three different polypyridyl ligands). Photolysis of [BzRu(pp)CI]Cl (Bz = eta (6)-C6H6) gives a mixture of Ru(pp)(CH3CN)(2)Cl-2 and [Ru(pp)(CH3CN)(3)Cl]Cl. Refluxing this mixture with pp' yields Ru(PP)(pp')Cl-2. Finally, refluxing Ru(pp)(pp')Cl-2 with pp " in a 75% ethanol/water solution gives [Ru(pp)(pp')(pp ")](2+). No ligand scrambling is observed. The complexes are characterized by H-1 NMR, elemental analysis, FAB-MB, UV-vis and emission spectroscopy, and cyclic voltammetry.

  DOI：

  10.1021/ic010603r