(1-(2-aminoethyl)-3-methylimidazolium)[tetrachloroaurate] | 1239384-03-2

• 英文名称: (1-(2-aminoethyl)-3-methylimidazolium)[tetrachloroaurate]
• 英文别名: (NH2(CH2)2ImMe)[AuCl4]
• CAS: 1239384-03-2
• 化学式: AuCl₄*C₆H₁₂N₃
• 分子量: 464.96
• InChiKey: ZGIYKMOHJXXBBG-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [gold(III)(chloride)3(1-(2-aminoethyl)-3-methylimidazolium)][tetrachloroaurate] 在 tetra(n-butyl)ammonium chloride 作用下， 以 二氯甲烷 为溶剂， 以91%的产率得到(1-(2-aminoethyl)-3-methylimidazolium)[tetrachloroaurate]
  参考文献：
  名称：

  A new gold(III)-aminoethyl imidazolium aurate salt: Synthesis, characterization and reactivity

  摘要：

  Tetrachloroauric acid HAuCl4 reacts with the ionic liquid 1-(2-aminoethyl)-3-methylimidazolium nitrate [NH2(CH2)(2)ImMe]NO3, (2b) or its dicationic ammonium salt [NH3(CH2)(2)ImMe][NO3](2), (3) in methanolic solutions to give the novel gold(III)-aminoethyl imidazolium aurate salt [Cl3AuNH2(CH2)(2)ImMe][AuCl4] (4). The reaction of 4 with [Bu-n(4)]Cl gives [NH2(CH2)(2)ImMe][AuCl4] (2c) whereas with acetone the dicationic, iminium-functionalized, imidazolium aurate salt [Me2C=N(H)(CH2)(2)ImMe][AuCl4](2) (5) has been isolated. The structures in the solid state of 2c, 3, 4, and 5 have been determined by X-ray diffraction. The electrochemical behaviour of 4 has been examined by Cyclic voltammetry in acetonitrile and compared with 2c and KAuCl4. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.02.001