{Pt2 Et2(μ-η5-C5H4P(C6H5)2)(μ-η1-1,1-C5H4P(C6H5)2)} | 141091-20-5

• 英文名称: {Pt2 Et2(μ-η5-C5H4P(C6H5)2)(μ-η1-1,1-C5H4P(C6H5)2)}
• CAS: 141091-20-5
• 化学式: C₃₈H₃₈P₂Pt₂
• 分子量: 946.827
• InChiKey: DMZJXCBAJKJQIG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  {Pt2 Et2(μ-η5-C5H4P(C6H5)2)(μ-η1-1,1-C5H4P(C6H5)2)} 在 carbon monoxide 作用下， 以 氯仿 为溶剂， 以94%的产率得到{diethyldicarbonyldi(μ-η1-diphenylphosphinocyclopentadienyl)diplatinum}
  参考文献：
  名称：

  Fallis, Kathleen A.; Anderson, Gordon K.; Lin, Minren, Organometallics, 1994, vol. 13, # 2, p. 478 - 488

  摘要：

  DOI：
• 作为产物：
  描述：

  {diethyldicarbonyldi(μ-η1-diphenylphosphinocyclopentadienyl)diplatinum} 以 氘代甲苯 为溶剂， 生成 {Pt2(CO)2(μ-η1-(diphenylphosphino)cyclopentadienyl)2} 、 {Pt2 Et2(μ-η5-C5H4P(C6H5)2)(μ-η1-1,1-C5H4P(C6H5)2)}
  参考文献：
  名称：

  Fallis, Kathleen A.; Anderson, Gordon K.; Lin, Minren, Organometallics, 1994, vol. 13, # 2, p. 478 - 488

  摘要：

  DOI：

文献信息

• Lin, Minren; Fallis, Kathleen A.; Anderson, Gordon K., Journal of the American Chemical Society, 1992, vol. 114, # 12, p. 4687 - 4693
  作者：Lin, Minren、Fallis, Kathleen A.、Anderson, Gordon K.、Rath, Nigam P.、Chiang, Michael Y.

  DOI：——

  日期：——
• Platinum Complexes Bridged by (Diphenylphosphino)cyclopentadienyl Ligands.Reactions with tert-Butyl Isocyanide or Phosphorus Ligands
  作者：Minren Lin、Kathleen A. Fallis、Gordon K. Anderson

  DOI：10.1021/om00015a017

  日期：1994.3

  The complexes [Pt2R2(mu-C5H4PPh2)2] (1) react with 2 equiv of CNBu(t) to form the face-to-face dimers [Pt2R2(CNBU(t))2(mu-eta1-C5H4PPh2)2] (2), in which the cyclopentadienyl rings of the bridging dppc ligands are 1,2-substituted by Pt and P. Addition of further CNBu(t) produces cis- and trans-[PtR(CNBU(t))2(C5H4PPh2-P)] (3), in which the dppc ligands are coordinated through the P atom only. Reactions of [Pt2R2(mu-C6H4PPh2)2] with phosphorus ligands proceed either to form complexes of the type [PtR(PR3')2(CrH4PPh2-P) or (by reductive elimination of the appropriate alkane) to produce the platinum(I) dimers [Pt2(PR3)2(mu-eta1-C6H4PPh2)2], the course of the reaction being dependent on the nature of the ligand and the solvent. Platinum(I) species of the type [Pt2(PR3)2(mu-eta1-C5H4PPh2)2] may be prepared alternatively by displacement of carbon monoxide from [Pt2(CO)2(mu-eta1-C5H4PPh2)2]. The NMR spectra of the platinum(1) compounds are discussed.