| 153371-30-3

• CAS: 153371-30-3
• 化学式: C₁₄H₁₈FeGe
• 分子量: 314.734
• InChiKey: CEIMFWHHRGRODJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  二茂铁 、 二乙基二氯化锗 在 正丁基锂 、 四甲基乙二胺 作用下， 以 正己烷 为溶剂， 生成
  参考文献：
  名称：

  二茂铁锗烷聚合物和共聚物

  摘要：

  Ferrocenylenegermane polymers and copolymers (1) have been prepared, in situ, by thermal treatment of the product from the reaction between dilithioferrocene and the corresponding R(2)GeCl(2), R = methyl (1a), ethyl (1b), n-butyl (1c), or their mixtures, Me(2)GeCl(2) + n-Bu(2)-GeC1(2) (1d) and Et(2)GeCl(2) + n-Bu(2)GeCl(2) (1e). Thin films of the polymers can exhibit both semicrystalline or amorphous morphology dependent upon the nature of the alkyl group and/or mode of casting. When cast from THF, 1c was observed as an amorphous material; however, after time a crystalline form was obtained. Films of mixed polymer systems, 1b + 1c, cast from THF immediately resulted in crystalline forms for both polymers, i.e., a seeding of 1c by 1b occurred. The diethyl/di-n-butyl copolymer was amorphous and elastomeric as was the dimethyl/di-n-butyl analog Cyclic voltammetry indicated the presence of two reversible redox couples in solution with potentials slightly higher than the Si analogs. The copolymers also exhibited distinctive electrochemistry and not a combination of the two individual components.

  DOI：

  10.1021/om00010a067