[Ru(η6-C10H14)Cl2(MePPri2)] | 302911-55-3

• 英文名称: [Ru(η6-C10H14)Cl2(MePPri2)]
• CAS: 302911-55-3
• 化学式: C₁₇H₃₁Cl₂PRu
• 分子量: 438.383
• InChiKey: WSLHPOLKUAGDHR-UHFFFAOYSA-L

反应信息

• 作为反应物：
  描述：

  4-氰基吡啶 、 ammonium hexafluorophosphate 、 [Ru(η6-C10H14)Cl2(MePPri2)] 以 甲醇 为溶剂， 以80%的产率得到[Ru(η6-C10H14)(MePPri2)Cl(CNC5H4N)]PF6
  参考文献：
  名称：

  Synthesis and spectroscopic properties of cationic Ru(II) arene complexes [Ru(η6-arene)(P)Cl(L)]+. (P=PPh3, PEt3, MePPri2 and L=4-cyanopyridine or 1,4-dicyanobenzene)

  摘要：

  Reactions of [Ru(eta(6)-arene)(P)Cl-2] (P = PPh3, PEt3 or MePPr'(2)) with organonitriles 4-cyanopyridine or 1,4-dicyanobenzene (referred hereafter as CNPy or DCB) in methanol, in the presence of NH4PF6, gives the cationic arene complexes [Ru(eta(6)-arene)(P)Cl(L)](+) (L = CNPy or DCB). The reaction products have been characterized by physico-chemical methods viz., elemental analyses, IR, H-1- C-13-, P-31-NMR, electronic and FAB mass spectra. The spectral data of the complexes revealed the presence of a pendant nitrile group. These could behave as potential metallo-ligands and could find wide application in the syntheses of homo- or heterobimetallic mixed valence bridged complexes. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(00)00258-8