trans-[Re(2-N(H2N)C6H4)Cl3(PPh3)2] | 211574-87-7

• 英文名称: trans-[Re(2-N(H2N)C6H4)Cl3(PPh3)2]
• CAS: 211574-87-7
• 化学式: C₄₂H₃₆Cl₃N₂P₂Re
• 分子量: 923.275
• InChiKey: UTSSVONDRCQNFR-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  trans-[ReOCl3(PPh3)2] 、 邻苯二胺 以 乙醇 为溶剂， 以61%的产率得到trans-[Re(2-N(H2N)C6H4)Cl3(PPh3)2]
  参考文献：
  名称：

  The reactivity of the [Re≡O]3+ core toward aromatic 1,2-diamines: the formation of rhenium(V)-imido complexes

  摘要：

  The reaction of the aromatic diamines 1,2-diaminobenzene, 2,3-diaminophenol (H2L), 2,3-diaminotoluene and 3,4-diaminobenzophenone (H2N-R-NH2) with trans-ReOCl3(PPh3)(2) in an equimolar ratio in ethanol gave the products trans-[Re(N-R-NH2)Cl-3(PPh3)(2)] in good yield. IR, H-1 NMR and X-ray crystallographic results indicate that the diamine ligands coordinate to rhenium(V) in a dianionic monodentate imido form. The structure of trans-[Re(L)Cl-3(PPh3)(2)] was determined and shows that only the deprotonated amino nitrogen in the 2-position of the potentially ambidentate 2,3-diaminophenol molecule is coordinated to the metal. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(97)06164-1