[(p-cymene)RuCl2]2(μ-1,2-di(2',2'-diethyl-1',3'-propanedioxy)phosphinoethane) | 500771-45-9

• 英文名称: [(p-cymene)RuCl2]2(μ-1,2-di(2',2'-diethyl-1',3'-propanedioxy)phosphinoethane)
• CAS: 500771-45-9
• 化学式: C₃₆H₆₀Cl₄O₄P₂Ru₂
• 分子量: 962.77
• InChiKey: LDVZMKNKGFEQIH-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  silver hexafluoroantimonate 、 [(p-cymene)RuCl2]2(μ-1,2-di(2',2'-diethyl-1',3'-propanedioxy)phosphinoethane) 以 二氯甲烷 为溶剂， 以45%的产率得到([(p-cymene)Ru(μ-Cl)]2(μ-1,2-di(2',2'-diethyl-1',3'-propanedioxy)phosphinoethane))[SbF6]2
  参考文献：
  名称：

  Synthesis and Structure of a Diphosphonite-Bridged Ruthenium Dication, {[(p-cymene)Ru(μ-Cl)]₂(μ-1,2-di(2‘2‘-diethyl-1‘,3‘-propanedioxy)phosphinoethane)}²⁺

  摘要：

  Attempted synthesis of [(p-cymene)Ru(PP)](2+) (PP = 1,2-di(2'2'-diethyl-1',3'-propanedioxy)phosphinoethane) by reaction of [(p-cymene)RuCl2](2) with PP followed by chloride abstraction with AgSbF6 afforded instead the diphosphonite-bridged Ru-II dimer, {[(p-cymene)Ru(mu-Cl)](2)(mu-PP)}[SbF6](2), which was structurally characterized. A neutral intermediate, [(p-cymene)RuCl2](2)-(mu-PP), was isolated and was converted to the latter by treatment with AgSbF6.

  DOI：

  10.1021/om020567j
• 作为产物：
  描述：

  dichloro(p-cymene)ruthenium(II) dimer 、 1,2-di(2',2'-diethyl-1',3'-propanedioxy)phosphinoethane 以 二氯甲烷 为溶剂， 以80%的产率得到[(p-cymene)RuCl2]2(μ-1,2-di(2',2'-diethyl-1',3'-propanedioxy)phosphinoethane)
  参考文献：
  名称：

  Synthesis and Structure of a Diphosphonite-Bridged Ruthenium Dication, {[(p-cymene)Ru(μ-Cl)]₂(μ-1,2-di(2‘2‘-diethyl-1‘,3‘-propanedioxy)phosphinoethane)}²⁺

  摘要：

  Attempted synthesis of [(p-cymene)Ru(PP)](2+) (PP = 1,2-di(2'2'-diethyl-1',3'-propanedioxy)phosphinoethane) by reaction of [(p-cymene)RuCl2](2) with PP followed by chloride abstraction with AgSbF6 afforded instead the diphosphonite-bridged Ru-II dimer, {[(p-cymene)Ru(mu-Cl)](2)(mu-PP)}[SbF6](2), which was structurally characterized. A neutral intermediate, [(p-cymene)RuCl2](2)-(mu-PP), was isolated and was converted to the latter by treatment with AgSbF6.

  DOI：

  10.1021/om020567j