[(C5Me4Et)Ru(μ2-κ2:η6-2,3-naphthalenediamido)Ru(C5Me4Et)] | 848899-49-0

• 英文名称: [(C5Me4Et)Ru(μ2-κ2:η6-2,3-naphthalenediamido)Ru(C5Me4Et)]
• CAS: 848899-49-0
• 化学式: C₃₂H₄₂N₂Ru₂
• 分子量: 656.839
• InChiKey: XXLNQWHWZICDPK-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  [((C5Me4Et)Ru)2(μ2-κ2:η4-2,3-naphthalenediamido)] 在 ((C5Me5)Ru)2(μ2-κ2:η4-2,3-(NH)2C10H6) 、 CH₃CN 作用下， 以 甲苯 为溶剂， 生成 [(C5Me4Et)Ru(μ2-κ2:η6-2,3-naphthalenediamido)Ru(C5Me4Et)]
  参考文献：
  名称：

  Dinuclear Ruthenium(II) κ²-Diamido/η⁶-Naphthalene Complexes Featuring a Coordinatively Unsaturated yet Highly π-Basic (η⁵-C₅Me₅)Ru Diamide Fragment

  摘要：

  Acetonitrile induces a clean isomerization of the amido-bridged diruthenium complex [(Cp*Ru)(2){mu(2)-kappa(2): eta(4)-2,3-naphthalenediamido}] (1) into the K-2:eta(6)-bonded dinuclear complex [Cp*Ru{mu(2)-k(2):eta(6)-2,3-naphthalenediamido}RuCp*] (2a), featuring a coordinatively unsaturated Cp*Ru terminal diamide fragment. Structural and spectroscopic data of its carbon monoxide and tert-butyl isocyanide adducts indicate that the Cp*Ru diamide,fragment can serve as a strong pi-base.

  DOI：

  10.1021/om049274b