8-(5-iodo-n-pentyl)-3-(η5-pentamethylcyclopentadienyl)-arachno-3-rhoda-7,8-dithiaundecaborane | 344592-13-8

• 英文名称: 8-(5-iodo-n-pentyl)-3-(η5-pentamethylcyclopentadienyl)-arachno-3-rhoda-7,8-dithiaundecaborane
• CAS: 344592-13-8
• 化学式: C₁₅H₃₄B₈IRhS₂
• 分子量: 594.865
• InChiKey: XHYYWTFZRSPHKE-RRKCIKGYSA-N

反应信息

• 作为产物：
  描述：

  dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer 、 在 N,N-N',N'-tetramethyl-1,8-diaminonaphthalene 作用下， 以 二氯甲烷 为溶剂， 以3%的产率得到8-(5-iodo-n-pentyl)-3-(η5-pentamethylcyclopentadienyl)-arachno-3-rhoda-7,8-dithiaundecaborane
  参考文献：
  名称：

  Ten-vertex rhodadithiaborane chemistry: [8-{I(CH₂)₅}-3-(η⁵-C₅Me₅)-arachno-3,7,8-RhS₂B₈H₉]

  摘要：

  Neutral 8-(5-iodo-n-pentyl)-3-(eta (5)-pentamethylcyclopentadienyl)-arachno-3-rhoda-7,8-dithiaundecaborane, [Rh(C(5)H(19)B(8)IS(2))(C(10)H(15))], obtained from the [arachno-7,8-S(2)B(9)H(10)](-) anion by treatment with I(CH(2))(5)I followed by [Rh(C(5)Me(5))Cl(2)](2) and N,N,N',N' -tetramethyl-1,8-diaminonaphthalene, has the 11-vertex cluster geometry of [arachno-7,8-S(2)B(9)H(10)](-), but with an {Rh(C(5)Me(5))} unit in the 3-position instead of a {BH} unit, and with a -(CH(2))(5)I chain attached exo to an S atom.

  DOI：

  10.1107/s010827010100244x