tert-butylimidotris(3,5-di-tert-butylpyrazolato)tantalum(V) | 355375-97-2

• 英文名称: tert-butylimidotris(3,5-di-tert-butylpyrazolato)tantalum(V)
• CAS: 355375-97-2
• 化学式: C₃₇H₆₆N₇Ta
• 分子量: 789.926
• InChiKey: JEOPBOXYFHNQSW-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  Ta(^tBu-imido)Cl₃(py)₂ 、 potassium 3,5-tert-butylpyrazolate 以 甲苯 为溶剂， 以77%的产率得到tert-butylimidotris(3,5-di-tert-butylpyrazolato)tantalum(V)
  参考文献：
  名称：

  Synthesis, structure, and properties of niobium and tantalum imido complexes bearing pyrazolato ligands. Crystal structures of Ta(Nt-Bu)(t-Bu2Pz)3, Ta(Ni-Pr)(t-Bu2Pz)3, Ta(Nt-Bu)(Me2Pz)3(py), and Ta(Nt-Bu)(t-Bu2Pz)2(Cl)(py)

  摘要：

  A series of tantalum and niobium imido complexes containing pyrazolato ancillary ligands has been synthesized by salt methathesis reactions with alkylimidotrichlorobis(pyridine)metal starting materials. The complexes M(Nt-Bu)(t-Bu(2)Pz)(3) (M = Nb, Ta), Ta(Ni-Pr)(t-Bu(2)Pz)(3). Ta(Nt-Bu)(Me(2)Pz)(3)(py), and M(Nt-Bu)(t-Bu(2)Pz)(2)(Cl)(py) (M = Nb. Ta) were prepared and completely characterized. The crystal and molecular structures of Ta(Nt-Bu)(t-Bu(2)Pz)(3). Ta(Ni-Pr)(t-Bu(2)Pz)(3). Ta(Nt-Bu)(Me(2)Pz)(3)(py), and Ta(Nt-Bu)(t-Bu(2)Pz)(2)(Cl)(py) are described. The potential use of tantalum imido pyrazolato complexes as precursors for the growth of tantalum nitride films by CVD techniques is discussed. (C) 2001 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(01)00695-7