[(μ-naphthalene-2-thiolato)2Fe2(CO)5PPh3] | 1421949-57-6

• 英文名称: [(μ-naphthalene-2-thiolato)2Fe2(CO)5PPh3]
• 英文别名: [(μ-naphthalene-2-thiolato)₂Fe₂(CO)₅PPh₃]
• CAS: 1421949-57-6
• 化学式: C₄₃H₂₉Fe₂O₅PS₂
• 分子量: 832.5
• InChiKey: OHBUUUYBQLLOGL-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [(μ-naphthalene-2-thiolato)2Fe2(CO)6] 、 三苯基膦 在 十二/十四烷基二甲基氧化胺 作用下， 以 乙腈 、 二氯甲烷 为溶剂， 反应 1.17h， 以40%的产率得到[(μ-naphthalene-2-thiolato)2Fe2(CO)5PPh3]
  参考文献：
  名称：

  Using naphthalene-2-thiolate ligands in the design of hydrogenase models with mild proton reduction overpotentials

  摘要：

  Diiron-carbonyl complexes coupled to naphthalene-2-thiolate ligands, [(mu-naphthalene-2-thiolato)(2)Fe-2(CO)(6)] (1) and [(mu-naphthalene-2-thiolato)(2)Fe-2(CO)(5)PPh3] (2), have been usefully prepared and structurally characterized. As models for the active site of hydrogenase enzymes, these compounds have been examined as electrocatalysts for the reduction of proton to produce molecular hydrogen. In the presence of acetic acid, 1 and 2 catalyze the electrochemical production of molecular hydrogen with mild overpotentials of -0.54 and -0.51 V versus Fc/Fc(+), respectively. The overpotential for compound 1 is 260 mV smaller than that of the analogous compound, [(mu-SPh)(2)Fe-2(CO)(6)]. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.11.001