| 876275-59-1

• CAS: 876275-59-1
• 化学式: C₃₀H₃₀Cl₂N₄O₂Pd₂
• 分子量: 762.34
• InChiKey: UOFNEBLCLCOAHO-XSHNIFCISA-L

反应信息

• 作为产物：
  描述：

  chloromethyl(1,5-cyclooctadiene)palladium(II) 、 以 二氯甲烷 为溶剂， 以80%的产率得到
  参考文献：
  名称：

  Bis-chelating ligands based on bipyridine or bis-isoquinoline moieties with controlled rotation around the C–C bond

  摘要：

  Two unprecedented types of ligands, with comparable essential coordination features, are proposed as supports for metal centres in bimetallic promotion of organic syntheses, including asymmetric catalytic processes. Synthesis and characterization of the bis-chelating bipyridine ligands A with C-2 symmetry and X-ray analysis of one bipyridine diimine palladium binuclear complex are described. Synthesis and X-ray analysis of the bis-phenylimino derivative of a dibenzodioxepine dialdehyde are also reported. This dialdehyde is a key intermediate in the attainment of bis-isoquinoline ligands B with the same symmetry as A. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2005.08.011