(1-[(2-thiomethyl)benzene]-3-[(4-methyl)benzene](triazenido)(chloro)palladium(II))2 | 945982-52-5

• 英文名称: (1-[(2-thiomethyl)benzene]-3-[(4-methyl)benzene](triazenido)(chloro)palladium(II))2
• CAS: 945982-52-5
• 化学式: C₂₈H₂₈Cl₂N₆Pd₂S₂
• 分子量: 796.449
• InChiKey: HNDOZOZGDWPOQJ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  双(乙腈)氯化钯(II) 、 1-[(2-thiomethyl)benzene]-3-[(4-methyl)benzene]triazene 在 Et₃N 作用下， 以 乙腈 为溶剂， 以59%的产率得到(1-[(2-thiomethyl)benzene]-3-[(4-methyl)benzene](triazenido)(chloro)palladium(II))2
  参考文献：
  名称：

  Binuclear Palladium(I) and Palladium(II) Complexes of ortho-Functionalized 1,3-Bis(aryl)triazenido Ligands

  摘要：

  Three new bis(aryl)triazene ligands, Ar-NNNH-Ar' [Ar = o-C6H4-CO2Me, Ar' = p-C6H4-CH3 (2); Ar = Ar' = o-C6H4-CO2Me (3); Ar = o-C6H4-SMe, Ar' = p-C6H4-CH3) (4)], have been synthesized. The reaction of 1-4 with PdCl2(NCCH3)(2) in the presence of a base afforded a series of binuclear diamagnetic palladium complexes. In these reactions, ligands 1-3 afforded the palladium(I) complexes [Pd-I(o-MeO2C-C6H4-NNN-o-C6H4-CO2Me)](2) (5, monoclinic, space group P2(1)/c, a = 8.6070(10) angstrom, b = 14.3220(10) angstrom, c = 12.7310(10) angstrom, beta = 100.2950(10)degrees, Z = 2), [Pd-I(o-MeO-C6H4-NNN-o-C6H4-OMe)](2) (6, triclinic, space group P1, a = 6.6288(5) angstrom, b = 10.2631(10) angstrom, c = 11.0246(11) angstrom, alpha = 85.579(6)degrees, beta = 80.885(6)degrees, gamma = 74.607(6)degrees, Z = 1), and [Pd-I(o-MeO2C-C6H4-NNN-p-C6H4-CH3)](2) (7, tetragonal, space group I41/a, a = 20.866(3) angstrom, b = 20.866(3) angstrom, c = 13.156(2) angstrom, Z = 8). In contrast, the reaction of ligand 4 with PdCl2(NCCH3)(2) resulted in the formation of a palladium(II) dimer, [Pd-II(o-MeS-C6H4-NNN-p-C6H4-CH3)Cl](2) (8, orthorhombic, space group P2(1)2(1)2, a = 10.4058(5) angstrom, b = 16.2488(8) angstrom, c = 9.9500(5) angstrom, Z = 2).

  DOI：

  10.1021/ic700516p