[Fe(octaethyloxyporphyrin)(hexafluoroantimonate)] | 939409-66-2

• 英文名称: [Fe(octaethyloxyporphyrin)(hexafluoroantimonate)]
• 英文别名: [Fe(OEOP)(SbF6)]
• CAS: 939409-66-2
• 化学式: C₃₅H₄₃F₆FeN₄OSb
• 分子量: 827.34
• InChiKey: DSBUELGAJVRCLB-SSKCFKABSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  盐酸 、 [Fe(octaethyloxyporphyrin)(hexafluoroantimonate)] 在 O₂ 作用下， 以 not given 为溶剂， 生成 [Fe(III)(octaethyloxyporphyrin)Cl2]
  参考文献：
  名称：

  Formation and stabilization of five-coordinate iron(II) verdoheme analogues by axial weakly coordinating anion ligation. X-ray crystal structures of [(OEOPFe)2O](X)2 (X=AsF6, SbF6)

  摘要：

  The effect of weakly coordinating anions, AsF6- and SbF6-, as axial ligands on the formation and coordination chemistry of verdoheme analogues have been examined. Two new five-coordinate and stable iron(II) verdoheme analogues, [(OEOPFeX)-X-II], where OEOP is the monoanion of octaethyloxoporphyrin and X = AsF6 and SbF6, have been isolated. The compounds have been characterized by different spectroscopic methods as well as elemental analysis. H-1 NMR spectroscopy and magnetic moment measurements show that the [(OEOPFeX)-X-II] are paramagnetic and iron is five-coordinate. Exposure of dichloromethane solutions of [(OEOPFeX)-X-II] (X = AsF6 (2), SbF6 (3)) to dioxygen result in their transformation into the mu-oxo bridged compounds, [(OEOPFe)(2)O](X)(2) (X = AsF6 (4), SbF6 (5)). The structures of 4 and 5 have been determined by X-ray diffraction analysis, both are structurally similar with a P2(1)/c space group in the monoclinic crystal system. (C) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2006.11.022
• 作为产物：
  描述：

  sodium hexafluoroantimonate 、 octaethylverdohemochrome 在 HF 作用下， 以 甲醇 、 二氯甲烷 为溶剂， 生成 [Fe(octaethyloxyporphyrin)(hexafluoroantimonate)]
  参考文献：
  名称：

  Formation and stabilization of five-coordinate iron(II) verdoheme analogues by axial weakly coordinating anion ligation. X-ray crystal structures of [(OEOPFe)2O](X)2 (X=AsF6, SbF6)

  摘要：

  The effect of weakly coordinating anions, AsF6- and SbF6-, as axial ligands on the formation and coordination chemistry of verdoheme analogues have been examined. Two new five-coordinate and stable iron(II) verdoheme analogues, [(OEOPFeX)-X-II], where OEOP is the monoanion of octaethyloxoporphyrin and X = AsF6 and SbF6, have been isolated. The compounds have been characterized by different spectroscopic methods as well as elemental analysis. H-1 NMR spectroscopy and magnetic moment measurements show that the [(OEOPFeX)-X-II] are paramagnetic and iron is five-coordinate. Exposure of dichloromethane solutions of [(OEOPFeX)-X-II] (X = AsF6 (2), SbF6 (3)) to dioxygen result in their transformation into the mu-oxo bridged compounds, [(OEOPFe)(2)O](X)(2) (X = AsF6 (4), SbF6 (5)). The structures of 4 and 5 have been determined by X-ray diffraction analysis, both are structurally similar with a P2(1)/c space group in the monoclinic crystal system. (C) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2006.11.022