cis,cis-[(RuCl2(CH3CN)2)2(phenylene-1,4-diaminotetra(phosphite)] | 1192481-35-8

• 英文名称: cis,cis-[(RuCl2(CH3CN)2)2(phenylene-1,4-diaminotetra(phosphite)]
• CAS: 1192481-35-8
• 化学式: C₇₀H₇₂Cl₄N₆O₁₆P₄Ru₂
• 分子量: 1721.22
• InChiKey: HWTHJSJELKYQMI-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂ 、 phenylene-1,4-diaminotetra(phosphonite) 、 乙腈 以 乙腈 为溶剂， 以81%的产率得到cis,cis-[(RuCl2(CH3CN)2)2(phenylene-1,4-diaminotetra(phosphite)]
  参考文献：
  名称：

  Di- and tetranulcear RuII complexes of phenylene-1,4-diaminotetra(phosphonite), p-C6H4[N{P(OC6H4OMe-o)2}2]2 and their catalytic investigation towards transfer hydrogenation reactions

  摘要：

  The stoichiometric reaction of phenylene-1,4-diaminotetra(phosphonite), p-C6H4[N{P(OC6H4OMe-o)(2)}(2)]2 (P2N Phi NP2) (1) with [RuCl2(p-cymene)](2) in acetonitrile produces cis, cis-[{RuCl2(CH3CN)(2)}(2)(P2N Phi NP2)] (2), whereas the similar reaction of 1 with [RuCl2(p-cymene)](2) in THF medium affords a tri-chloro-bridged tetrametallic complex, [{(eta(6)-p-cymene)Ru-2(mu(2)-Cl)(3)Cl}(2)(P2N Phi NP2)] (3) irrespective of the stoichiometry and reaction conditions. The formation and structure of complexes 2 and 3 are assigned through various spectroscopic and micro analysis data. The molecular structure of 2 is confirmed by single crystal X-ray diffraction study. The catalytic activities of complexes 2 and 3 have been investigated in transfer hydrogenation reactions. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2009.07.002