N,N'-bis[(2-dodecylthio)phenylmethylene]-1,2-ethanediaminenickel(II) bromide | 335328-00-2

• 英文名称: N,N'-bis[(2-dodecylthio)phenylmethylene]-1,2-ethanediaminenickel(II) bromide
• CAS: 335328-00-2
• 化学式: C₄₀H₆₄Br₂N₂NiS₂
• 分子量: 855.592
• InChiKey: GQTOUYLCTONZEH-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  N,N'-bis[(2-(dodecylthio)phenyl)methylene]-1,2-ethanediamine 、 nickel dibromide 以 乙醇 、 二氯甲烷 为溶剂， 以46%的产率得到N,N'-bis[(2-dodecylthio)phenylmethylene]-1,2-ethanediaminenickel(II) bromide
  参考文献：
  名称：

  Functional nickel thiosalen complexes: structure and solid-state packing of a transition metal-based surfactant

  摘要：

  The complex NiBr2(2-C12H25SC6H4CH=NCH2CH2N=CHC6H4SC12H25-2) (1) was prepared from the ligand 2-C12H25SC6H4CH=NCH2CH2N=CHC6H4SC12H25-2 (3) and NiBr2. Paramagnetic 1 was characterized by combustion analyses, H-1 and C-13 NMR spectroscopy, Vis-NIR spectroscopy, measurement of its magnetic susceptibility, and single-crystal X-ray diffraction. The crystal structure of 1 features octahedral coordination of Ni(II) with axial bromides and fully extended interdigitated alkyl chains. There are significant differences between the solid state structures of 1 and NiBr2(2-C6H12SC6H4CH=NCH2CH2N=CHC6H4SC6H12-2) (2), a previously reported homologue. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(00)00342-x