[(η6-C6H5(CH2)3NHTf)RuCl2]2 | 1078722-26-5

• 英文名称: [(η6-C6H5(CH2)3NHTf)RuCl2]2
• CAS: 1078722-26-5
• 化学式: C₂₀H₂₄Cl₄F₆N₂O₄Ru₂S₂
• 分子量: 878.496
• InChiKey: MBPZWJJUFSVJOE-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [(η6-C6H5(CH2)3NHTf)RuCl2]2 、 乙腈 以 乙腈 为溶剂， 生成 [η6:η1-C6H5(CH2)3NTf]RuCl(CH3CN)
  参考文献：
  名称：

  Well-Defined Triflylamide-Tethered Arene−Ru(Tsdpen) Complexes for Catalytic Asymmetric Hydrogenation of Ketones

  摘要：

  Well-defined triflylamide-tethered arene-Ru(Tsdpen) complexes have been developed as highly efficient catalysts for the asymmetric hydrogenation of ketones, in which the suitable carbon chain length of the tether is responsible for the activation of H, as well as the stereochemical outcome of the reaction. The asymmetric hydrogenation of aromatic ketones with the tethered complex with a C-4 side chain gave the corresponding secondary alcohols with 91-98% ee, while the shorter congeners with a C-2 or C-3 side chain provided unsatisfactory results in tems of reactivity and selectivity.

  DOI：

  10.1021/om800735z
• 作为产物：
  描述：

  水合三氯化钌 、 以 not given 为溶剂， 生成 [(η6-C6H5(CH2)3NHTf)RuCl2]2
  参考文献：
  名称：

  Well-Defined Triflylamide-Tethered Arene−Ru(Tsdpen) Complexes for Catalytic Asymmetric Hydrogenation of Ketones

  摘要：

  Well-defined triflylamide-tethered arene-Ru(Tsdpen) complexes have been developed as highly efficient catalysts for the asymmetric hydrogenation of ketones, in which the suitable carbon chain length of the tether is responsible for the activation of H, as well as the stereochemical outcome of the reaction. The asymmetric hydrogenation of aromatic ketones with the tethered complex with a C-4 side chain gave the corresponding secondary alcohols with 91-98% ee, while the shorter congeners with a C-2 or C-3 side chain provided unsatisfactory results in tems of reactivity and selectivity.

  DOI：

  10.1021/om800735z