(PdCl(η3-C3H5)(Ph2PCH2CH(Ph)NHPh-κP)) | 337379-40-5

• 英文名称: (PdCl(η3-C3H5)(Ph2PCH2CH(Ph)NHPh-κP))
• CAS: 337379-40-5
• 化学式: C₂₉H₂₉ClNPPd
• 分子量: 564.403
• InChiKey: HOCNGBIEMSCGBQ-DOTPTTDOSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  bis(η3-allyl-μ-chloropalladium(II)) 、 (2-Anilino-2-phenylethyl)diphenylphosphine 以 二氯甲烷 为溶剂， 以71%的产率得到(PdCl(η3-C3H5)(Ph2PCH2CH(Ph)NHPh-κP))
  参考文献：
  名称：

  Synthesis of β-P,N Aminophosphines and Coordination Chemistry to Pd^II. X-ray Structures of [PdCl₂(Ph₂PCH₂CH(Ph)NHPh-κP,κN)] and [PdCl(η³-C₃H₅)(Ph₂PCH₂CH(Ph)NHPh-κP)]

  摘要：

  The reaction of the C=N bond in PhCH=NPh with the carbanionic species Ph2PCH2-, leading to the N-phenyl beta -aminsphosphine Ph2PCH2CH(Ph)NHPh, L-1, is described. This molecule reacts with different organic electrophiles to afford related compounds Ph2PCH2CH(Ph)NPhX (X = SiMe3, L-2; COPh, L-4), [Ph2MePCH2CH(Ph)NHPh](+)(I-), L-3, and [Ph2PCH2CH(Ph)N(Ph)CO](2), L-5, containing two amido and two phosphino functions. The coordination properties of L-1, L-2, and L-4 have been studied in palladium chemistry. The X-ray structure of [PdCl2(Ph2PCH2-CH(Ph)NHPh-kappaP,kappaN)I shows the bidentate coordination mode for the L-1 Ligand with equatorial C-Ph-N-Ph phenyl groups. [PdCl2(Ph2PCH2CH(Ph)NHPh-kappaP,kappaN)] crystallizes at 298 K in the space group P2(1)/n with cell parameters a = 10.689(2) Angstrom, b = 21.345(3) Angstrom, c = 12.282(2) Angstrom, beta = 90.294(1.2)degrees Z = 4, D-calcd = 1.526. The reaction between 2 equiv of L-1 and [PdCl(eta (3)-C3H5)](2) affords the [PdCl(eta (3)-C3H5)(Ph2PCH2CH(Ph)NHPh-kappaP)] complex in which an unexpected N-H . . . Cl intramolecular interaction has been observed by an X-ray diffraction analysis. [PdCl(eta (3)-C3H5)(Ph2PCH2CH(Ph)NHPh-kappaP)] crystallizes at 298 K in the monoclinic space group Cc with cell parameters a = 10.912(1) Angstrom, b = 17.194(2) Angstrom, c = 14.169(2) Angstrom, beta = 100.651(9)degrees Z = 4, D-calcd = 1.435. Neutral and cationic alkyl or allyl palladium chloride complexes containing L-1 are also reported as well as a neutral allyl palladium chloride complex containing L-4. Variable-temperature P-31{H-1} NMR studies on the allyl complexes show that the eta (3)/eta (1) allyl interconversion is enhanced by a positive charge and also by a N-H . . . Cl intramolecular interaction.

  DOI：

  10.1021/ic000867y