aluminum tris(3-chloromethylthio-2,4-pentanedionate) | 421553-74-4

• 英文名称: aluminum tris(3-chloromethylthio-2,4-pentanedionate)
• CAS: 421553-74-4
• 化学式: C₁₈H₂₄AlCl₃O₆S₃
• 分子量: 565.923
• InChiKey: ZIIIMNHSFBZVOZ-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  重氮甲烷 、 aluminum tris(3-chlorosulfenyl-2,4-pentanedionate) 以 乙醚 、 氯仿 为溶剂， 以48%的产率得到aluminum tris(3-chloromethylthio-2,4-pentanedionate)
  参考文献：
  名称：

  摘要：

  SCI-Substituted chromium(III), cobalt(III), and aluminum(III) acetylacetonates react with carbenes similarly to organylsulfenyl chlorides, with insertion of the carbenes into the S-Cl bond. Reaction with diazomethane gave chloromethylthio-substituted complexes whose structure was proved by IR, H-1 NMR, and mass spectroscopy. The thermal oxidative degradation of the complexes was studied. Chlorination of SCH3-substituted acetylacetonates does not yield such complexes.

  DOI：

  10.1023/a:1013941600121