[Cu2(bpyr)Cl2] | 54217-38-8

• 英文名称: [Cu2(bpyr)Cl2]
• 英文别名: [Cu2(2,2'-bipyrimidine)Cl2]
• CAS: 54217-38-8
• 化学式: C₈H₆Cl₂Cu₂N₄
• 分子量: 356.16
• InChiKey: MRLJVTNGKDYYIK-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  copper(II) choride dihydrate 、 2 2'-联嘧啶 在 4,4'-bipyridine 作用下， 以 水 为溶剂， 以50%的产率得到[Cu2(bpyr)Cl2]
  参考文献：
  名称：

  Solid state coordination chemistry of the oxovanadium-diphosphonate/copper-bipyrimidine system: Crystal structures of [{Cu2(bpyr)}VO(H2O)(HO3PCH2PO3)2] and [{Cu2(bpyr)}{Cu2(bpyr)(H2O)2}(VO2)2(HO3PCH2PO3)2(HO3PCH2PO3H)2]

  摘要：

  Hydrothermal chemistry has been exploited in the preparation of two materials of the copper(II)-bipyrimidine/oxovanadium-organophosphonate family, the two dimensional [{Cu(bpyr)}VO(H2O)(HO3PCH2PO3)(2)] (1) and the three-dimensional [{Cu-2(bpyr)}{Cu-2(bpyr)(H2O)(2)}(VO2)(2)(HO3PCH2PO3)(2)-(HO3PCH2PO3H)(2)] center dot 2H(2)O (2 . 2H(2)O) (bpyr = 2,2'-bipyrimidine). The structure of 1 may be described as [{Cu-2(bpyr)}Cu-2(bpyr)O-4}(n)(4n+) chains linked through {VOIV(H2O)(HO3 PCH2PO3)(2)}(4) units. In contrast, the structure of 2 consists of {Cu-2(bpyr)}(2+), {Cu-2(bpyr)(H2O)(2)}(2+) and {(VO2)-O-V(HO3PCH2PO3)-(HO3PCH2PO3H)}(4) subunits linked into a framework architecture.The vanadium component of the reaction mixture failed to incorporate into the two-dimensional structure of [{Cu(bpyr)(H2O)(2)}{HO3PCH2CH2PO3H}(2)](3). The architecture of 3 consists of '4+ 2' distorted octahedral Cu(II) sites linked through bpyr and diphosphonate ligands into a network. [Cu-2(bpyr)Cl-2] (4) is a simple one-dimensional ribbon constructed from parallel {CuCl}(n) chains linked by bpyr ligands. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2008.08.032