N-allylquinolinium CuCl3 N-allylquinoline | 411208-53-2

• 英文名称: N-allylquinolinium CuCl3 N-allylquinoline
• CAS: 411208-53-2
• 化学式: C₉H₇Cl₃CuN*C₁₂H₁₂N
• 分子量: 469.3
• InChiKey: GPJLAVDWZHSKFC-UHFFFAOYSA-K

反应信息

• 作为产物：
  描述：

  (N-allylquinolinium)2 CuCl4 以 乙醇 、 苯 为溶剂， 生成 N-allylquinolinium CuCl3 N-allylquinoline
  参考文献：
  名称：

  摘要：

  The crystals of [C9H7N(C3H5)](2)(CuCl4)-Cl-II (IV) were obtained through ac electrochemical synthesis using CuCl2. 2H(2)O, N-allylquinolinium chloride, and copper electrodes in an ethanol-benzene medium. These crystals transformed with time into crystals of the [C9H7N(C(3)H5)j1Cu(II)Cl(3)(C9H7N)] complex (V). When tin(II) chloride was added to the initial reagents, the [C9H7N(C3H5)]Cu-2(I) Cl-3 Complex (VI) was obtained. The X-ray diffraction analysis (DARCh-I autodiffractometer, MoKalpha radiation, Zr filter) indicated that complexes IV and V crystallize in the triclinic system: space group P (1) over bar; for IV, a = 12.817(4), b = 10.435(3), c = 9.606(3) Angstrom, alpha = 97.94(2)degrees, beta = 107.28(2)degrees, gamma = 95.99(2)degrees, V = 1200.6(6) Angstrom (3), Z = 2; for V, a = 16.992(5), b = 8.243(2), c = 7.345(3) Angstrom, alpha = 91.89(3)degrees, beta = 91.19(3)degrees, gamma = 88.18(3)degrees, V = 1027.5(6) Angstrom (3), Z = 2. Crystals VI are monoclinic, space group P2(1)/n, a = 13.578(5), b = 15.079(4), c = 6.953(4) Angstrom, beta = 105.08(4)degrees, V = 1370.6(10) Angstrom (3), Z = 4. Structures IV-VI consist of N-allylquinolinium cations and different anions: isolated [CuCl4](2-) tetrahedrons (IV), [C9H7NCuCl3](-) tetrahedrons (V) containing a quinoline molecule, and a polymer chain ([Cu-4(I) Cl-6](2-))(n) (VI) in which two independent metal atoms have trigonal-pyramidal and planar-trigonal environments. The C=C bond of the allyl group is not involved in cooordination with the Cu(I) atom.

  DOI：

  10.1023/a:1013065129446