| 869730-72-3

• CAS: 869730-72-3
• 化学式: C₂₁H₂₀ClN₃OPd
• 分子量: 472.282
• InChiKey: SLROYRWFKLRBDN-KPOOZVEVSA-M

反应信息

• 作为产物：
  描述：

  sodium tetrachloropalladate(II) 、 N-[(2-methoxyphenyl)methyl]-2-[(4-methylphenyl)diazenyl]aniline 以 甲醇 为溶剂， 以45%的产率得到
  参考文献：
  名称：

  A strategy of Pd(II) assisted C–H activation in 2-alkylamino azobenzene ligands: Syntheses, characterisation and structure of a new family of orthopalladated complexes

  摘要：

  Several 2-(arylazo)-N-alkyl aniline ligands, 1a-11a, have been prepared by the reaction between 2-(arylazo) aniline and the appropriate alkyl halide in the presence of K2CO3. Treatment of sodium tetrachloropallaclate with 1a-11a in methanol afforded the orthopalladated complexes 1b-11b, where the ligand is tridentate (C,N,N). The ligands and complexes were characterised from spectroscopic data and confirmed by X-ray studies. The X-ray Structure of 9b displayed an unsupported Pd(II)Pd-...(II) interaction (3.301 angstrom). (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2005.05.022