| 848899-37-6

• CAS: 848899-37-6
• 化学式: C₂₈H₂₂Cu₂N₆O₂
• 分子量: 601.614
• InChiKey: FSKQEUITNJJPED-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  甲醇 、 、 copper diacetate 以 甲醇 为溶剂， 生成
  参考文献：
  名称：

  New Binuclear Cu(II) Complexes with Bis(hetarylhydrazones) of 2,6-Diformyl-4-Methylphenol

  摘要：

  A series of new binuclear complexes of copper(II) acetate and chloride with bis(hydrazones) based on heterocyclic hydrazines were synthesized. Magnetochemical analysis showed that the resulting metal chelates with different bridging atoms in the exchanged fragment significantly differ in exchange parameters. This fact was explained in terms of geometrical structures of complexes of both types.

  DOI：

  10.1023/b:ruco.0000047472.21474.e0

文献信息

• New binuclear metal chelate complexes of copper(II) chloride and acetate with bis(hetarylhydrazones) obtained by condensation of 2,6-diformyl-4-r-phenols with 2-hydrazinoquinoline
  作者：V. V. Lukov、I. E. Gevorkyan、E. V. Dontsova、V. A. Koga、L. D. Popov、V. V. Dykov

  DOI：10.1007/s11173-005-0012-7

  日期：2005.2

  A spectrophotometric study of heteroligand chromium(III) complexes with iminodiacetic (H2Ida), N-methyliminodiacetic (H2Mida), N -(β-hydroxyethyl)iminodiacetic (H2Heida), nitrilotriacetic (H3Nta), ethylenediaminetetraacetic (H4Edta), and citric acids (H4Cit) showed that complexation in ternary systems depends on the concentrations of the reagents and the pH of the medium. The resulting complexes were [Cr(HIda)(H2Cit)], [Cr(HMida)(H2Cit)], [Cr(HHeida)(H2Cit)], [Cr(HHeida)(HCit)]–, [Cr(HNta)(H2Cit)]–, [Cr(HNta)(HCit)]2–, [Cr(Nta)(HCit)]3–, [Cr(HEdta)(HCit)]3–, and [Cr(Edta)(HCit)]4–. The logarithms of their stability constants are 41.97 ±0.47, 43.54 ±0.62, 42.32 ±0.62, 36.34 ±0.26, 43.70 ±0.25, 39.75 ±0.45, 32.93 ±1.56, 46.46 ±0.80, and 41.71 ±0.81 , respectively (I = 0.1 (NaClO 4)).

  分光光度法研究了异配体铬（III）与亚氨基二乙酸（H2Ida）、N-甲基亚氨基二乙酸（H2Mida）、N-（β-羟乙基）亚氨基二乙酸（H2Heida）、次氮基三乙酸（H3Nta）、乙二胺四乙酸（H4Edta）和柠檬酸（H4Cit）的络合物、乙二胺四乙酸（H4Edta）和柠檬酸（H4Cit）表明，三元体系中的络合取决于试剂的浓度和介质的 pH 值。它们的稳定常数对数分别为 41.97 ±0.47、43.54 ±0.62、42.32 ±0.62、36.34 ±0.26、43.70 ±0.25、39.75 ±0.45、32.93 ±1.56、46.46 ±0.80、41.71 ±0.81（I = 0.1（NaClO 4））。