| 1513868-26-2

• CAS: 1513868-26-2
• 化学式: C₁₈H₁₅ClFeN₃O₃S
• 分子量: 444.701
• InChiKey: ISBFNDWMEJQKNG-DXSCRKASSA-K

反应信息

• 作为反应物：
  描述：

  生成
  参考文献：
  名称：

  Co(III) and Fe(III) complexes of Schiff bases derived from 2,4-dihydroxybenzaldehyde S-allyl-isothiosemicarbazonehydrobromide

  摘要：

  Two new complexes, [Co(L-1)(Py)(3)]Cl0.75Br0.25 (L-1=4-hydroxy salicylaldehyde S-allyl-isothiosemicarbazonato-N,N,O) and [Fe(L-2)Cl]C2H5OH (L-2=S-allyl-N-1-(4-hydroxy salicylaldehyde)-N-4-(salicylaldehyde)isothiosemicarbazide-N,N,O,O), have been synthesized and characterized by elemental analysis, FT-IR and UV-vis spectroscopy, and molar conductivity. The solid-state structures of the complexes were also determined by single crystal X-ray diffraction. The iron(III) and cobalt(III) complexes adopt distorted square-pyramidal and octahedral geometries, respectively. The strength of the bonding in these complexes was investigated by thermogravimetric studies with both exhibiting stability with complete decomposition not occurring until ca. 600 degrees C.

  DOI：

  10.1080/00958972.2013.856420
• 作为产物：
  描述：

  chloro-(S-allyl-N¹-(4-hydroxysalicylaldehyde)-N⁴-(salicylaldehyde)isothiosemicarbazide-N,N',O,O')iron(III) ethanol 生成
  参考文献：
  名称：

  Co(III) and Fe(III) complexes of Schiff bases derived from 2,4-dihydroxybenzaldehyde S-allyl-isothiosemicarbazonehydrobromide

  摘要：

  Two new complexes, [Co(L-1)(Py)(3)]Cl0.75Br0.25 (L-1=4-hydroxy salicylaldehyde S-allyl-isothiosemicarbazonato-N,N,O) and [Fe(L-2)Cl]C2H5OH (L-2=S-allyl-N-1-(4-hydroxy salicylaldehyde)-N-4-(salicylaldehyde)isothiosemicarbazide-N,N,O,O), have been synthesized and characterized by elemental analysis, FT-IR and UV-vis spectroscopy, and molar conductivity. The solid-state structures of the complexes were also determined by single crystal X-ray diffraction. The iron(III) and cobalt(III) complexes adopt distorted square-pyramidal and octahedral geometries, respectively. The strength of the bonding in these complexes was investigated by thermogravimetric studies with both exhibiting stability with complete decomposition not occurring until ca. 600 degrees C.

  DOI：

  10.1080/00958972.2013.856420