bis[di(μ-methyltellurolato)-cyclopentadienylvanadium] | 286434-49-9

• 英文名称: bis[di(μ-methyltellurolato)-cyclopentadienylvanadium]
• CAS: 286434-49-9
• 化学式: C₂₄H₄₂Te₄V₂
• 分子量: 942.88
• InChiKey: JNWKLARKTXIQJE-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  二甲基二碲化物 、 bis[(μ-methyltellurolato)-pentamethylcyclopentadienyl-dicarbonyl-vanadium] 以 甲苯 为溶剂， 生成 bis[di(μ-methyltellurolato)-cyclopentadienylvanadium]
  参考文献：
  名称：

  Binuclear CpV, Cp*V, and Cp*Ta Complexes containing Organochalcogenolato Bridges, μ-ER (E = Sulfur, Selenium, Tellurium; R = Methyl, Phenyl, and Ferrocenyl)

  摘要：

  Photolysis of the halfsandwich tetracarbonylmetal complexes CpV(CO)(4), Cp*V(CO)(4) and Cp*Ta(CO)(4) in solution in the presence of di(organyl)dichalcogenides E2R2 (E = S, Se, Te; R = Me, Ph, Fc) leads to diamagnetic doubly organochalcogenolato-bridged compounds, [(CpM)-M-0(CO)(2)(mu-ER)](2). According to the X-ray structure determinations carried out for [CpV(CO)-L(mu-TeMe)](2), [Cp*V(CO)(2)(mu-TePh)](2) and [Cp*Ta(CO)(2)(mu-SPh)](2), the molecular framework consists of a folded M-2(mu-ER)(2) ring with the cyclopentadienyl ligands in cis-configuration and the organyl substituents R in a syn-equatorial arrangement, thus forming a bowl-shaped molecule with the four terminal CO ligands protruding into the inner sphere. The M ... M distances (in the range between 305 and 330 pm) are not considered to indicate direct bonding interactions. The vanadium complexes [(CpV)-V-0(CO)(2)(mu-ER)](2) are completely decarbonylated in the presence of an excess of E2R2 in boiling toluene, and in many cases the paramagnetic quadruply-bridged products, [CpV(mu-ER)(2)](2), can be isolated.

  DOI：

  10.1002/(sici)1521-3749(200006)626:6<1289::aid-zaac1289>3.0.co;2-o