De, Rajib Lal; Wolters, Doris; Vahrenkamp, Heinrich, Zeitschrift fur Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, 1986, vol. 41, # 3, p. 283 - 291
作者:De, Rajib Lal、Wolters, Doris、Vahrenkamp, Heinrich
DOI:——
日期:——
Insertion of SO2 into the P–P bond of Fe2(CO)6(μ-P2 tBu2)
作者:Shariff E Kabir、Michael Ruf、Heinrich Vahrenkamp
DOI:10.1016/s0022-328x(99)00173-4
日期:1999.7
The P-P bond in the dinuclear iron complex Fe-2(CO)(6)(mu-(P2Bu2)-Bu-t) was found to be labile towards SO2 insertion, yielding Fe-2(CO)(6)(mu-(BuP)-Bu-t-SO2-(PBu)-Bu-t), which was characterized by a structure determination. (C) 1999 Elsevier Science S.A. All rights reserved.
Spaltung von diazen- und diphosphen-liganden bei der cluster-expansion
作者:Bernhard Hansert、Heinrich Vahrenkamp
DOI:10.1016/0022-328x(93)83155-o
日期:1993.11
The mu-E(2)R(2) bridged complexes Fe-2(CO)(6)(N(2)Ph(2)) (1a) and Fe-2(CO)(6)(P(2)(t)Bu(2)) (1b) undergo cluster expansion, with Fe-2(CO)(9) in hexane, to form the mu(3)-eta(2) bridged clusters Fe-3(CO)(9)(N(2)Ph(2)) (2a) and Fe-3(CO)(9)(P(2)(t)Bu(2)) (2b). Both clusters 2 are unstable in solution, being converted quantitatively with N-N or P-P cleavage into the bis-mu(3) bridged clusters Fe-3(CO)(9)(NPh)(2) (3a) and Fe-3(CO)(9)(P(t)Bu)(2) (3b) respectively.