[Cu(II)(1,2-bis(pyridylsulfanyl)benzene)Cl2]*methanol | 696605-51-3

• 英文名称: [Cu(II)(1,2-bis(pyridylsulfanyl)benzene)Cl2]*methanol
• CAS: 696605-51-3
• 化学式: CH₄O*C₁₈H₁₆Cl₂CuN₂S₂
• 分子量: 490.965
• InChiKey: LBKJDERPDFBXMG-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  甲醇 、 copper(II) choride dihydrate 、 1,2-bis(2-pyridylsulfanylmethyl)benzene 以 甲醇 为溶剂， 以83%的产率得到[Cu(II)(1,2-bis(pyridylsulfanyl)benzene)Cl2]*methanol
  参考文献：
  名称：

  Copper(II) complexes of bis- and tetrakis-(2-pyridylsulfanylmethyl)benzenes

  摘要：

  Reactions of copper(II) salts with the ligand 1,2-bis(2-pyridylsulfanylmethyl)benzene (L-1) and the isomeric ligands 1,2,3,4-tetrakis(2-pyridylsulfanylmethyl)benzene (L-2) and 1,2,4,5-tetrakis(2-pyridylsulfanylmethyl)benzene (L-3) give copper(II) complexes, some of which have been characterised by X-ray crystallography. [Cu(L-1)Cl-2] is found to be a one-dimensional coordination polymer, containing two subtly different copper atom environments. By contrast, [Cu-2(L-2)Cl-4] and [Cu-2(L-3)(NO3)(4)] are discrete species with, in each case, the copper atoms chelated by adjacent ligand arms. (C) 2003 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2004.01.001