Versatile Behavior of β-Heterosubstituted Zirconaindene Complexes: M−Cl Bond Activation (M = Si, P, Au Fragments)
作者:Krzysztof Owsianik、Maria Zablocka、Alain Igau、Jean-Pierre Majoral、Aleksandra Skowronska
DOI:10.1002/1099-0682(200107)2001:7<1693::aid-ejic1693>3.0.co;2-f
日期:2001.7
A new way of M-Cl bond activation (M = Si, E Au fragments) is reported. It: consists on the 1,2-addition of M-Cl containing species on the Zr-N bond of azazirconaindene complexes. Unprecedented imino gold complexes incorporating two electron-deficient metallic centers (Au, Zr) have been prepared.