[(indenyl)Mo(η4-C5H5-exo-CH2Cl)(dppe)]BF4 | 933782-72-0

• 英文名称: [(indenyl)Mo(η4-C5H5-exo-CH2Cl)(dppe)]BF4
• 英文别名: [(indenyl)Mo(η4-C5H5-exo-CH2Cl)(1,2-bis(diphenylphosphino)ethane)]BF4
• CAS: 933782-72-0
• 化学式: BF₄*C₄₁H₃₈ClMoP₂
• 分子量: 810.898
• InChiKey: WOZCBJBJRRUTNP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  二氯甲烷 、 [(indenyl)Mo(η4-C5H6)(1,2-bis(diphenylphosphino)ethane)]BF4 以 二氯甲烷 为溶剂， 以97%的产率得到[(indenyl)Mo(η4-C5H5-exo-CH2Cl)(dppe)]BF4
  参考文献：
  名称：

  Synthesis and structural characterization of new mixed-ring indenyl derivatives of molybdenum containing phosphorus ligands

  摘要：

  Reaction of NaBH4 with [IndCpMo(dppe)](BF4)(2) (1) in acetone yields [IndMo(eta(4)-C5H6)(dppe)]BF4 (2) quantitatively. The hydride addition takes place at the external face of the Cp ring. Dissolution of 2 in dichloromethane gives [IndMo(eta(4)-C5H5-exo-CH2Cl)(dppe)]BF4, as confirmed by elemental analysis, IR and H-1 NMR spectroscopy. The similar dication [IndCpMo- {P(OMe)(3))(2)](BF4)(2) (4) reacts with NaBH4, in a solvent dependent manner. In acetonitrile, [IndMo(eta(4)-C5H6){P(OMe)(3)}(2)]BF4 (5) is obtained and in acetone a P(OMe)(3) ligand is lost resulting in the asymmetric phosphite-hydride, [IndCpMoH{P(OMe)(3)}](+) (6). The molecular structures of [IndMo(eta(4)-C5H6){P(OMe)(3)}(2)]PF6 and [IndCpMoH{P(OMe)(3)}]PF6 were characterized by single-crystal X-ray diffraction. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2006.12.015