[OsCl(η⁵-C₅H₅)(PⁱPr₃)(CO)] | 173675-51-9

• 英文名称: [OsCl(η⁵-C₅H₅)(PⁱPr₃)(CO)]
• CAS: 173675-51-9
• 化学式: C₁₅H₂₆ClOOsP
• 分子量: 478.998
• InChiKey: VCIFLIMXFUHRAO-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [OsCl(η⁵-C₅H₅)(PⁱPr₃)(CO)] 、 dimethyl 2-(2-oxoethyl)-2-(prop-2-yn-1-yl)malonate 在 silver tetrafluoroborate 作用下， 以 二氯甲烷 为溶剂， 以94%的产率得到[Os(η⁵-C₅H₅)(PⁱPr₃)(CO)(CC₅H₆O(CO₂Me)₂)][BF₄]
  参考文献：
  名称：

  Osmium-Centered Oxetylidene: Formation and Cleavage

  摘要：

  The first transition-metal oxetylidene complex has been prepared by reaction of OsCl(eta(5)-C5H5)(CO)((PPr3)-Pr-i) with 3,3-di(methoxycarbonyl)-5-hexyn-1-al and AgBF4. This novel compound is transformed into a hydroxyalkenylcarbene isomer by deprotonation and subsequent protonation of the resulting alpha,beta-unsaturated acyl transient species. In fluorobenzene at 90 degrees C, the four-membered ring undergoes cycloreversion to afford a cis-dicarbonyl derivative and the cycloalkene.

  DOI：

  10.1021/om3011323
• 作为产物：
  描述：

  四氯化碳 、 以 正己烷 为溶剂， 以72%的产率得到[OsCl(η⁵-C₅H₅)(PⁱPr₃)(CO)]
  参考文献：
  名称：

  New Cyclopentadienylosmium Derivatives Prepared from the Five-Coordinate Complex [OsHCl(CO)(PPrⁱ₃)₂]

  摘要：

  The reaction of [OsHCl(CO)(PPr3i)(2)] (1) with cyclopentadiene in refluxing methanol affords the novel cyclopentadienylosmium(II) complex [OsH(eta(5)-C5H5)(CO)-(PPr3i)] (2). Reaction of 2 with CCl4 in pentane gives the chloro complex [Os(eta(5)-C5H5)Cl(CO)(PPr3i)] (3). The protonation of 2 with HBF4.Et(2)O leads to the transdihydridoosmium(IV) complex[OsH2(eta(5)-C(5)H5)(CO)(PPr3i)]-BF (4). Treatment of the chloro complex 3 with AgBF4 followed by the terminal alkyne phenylacetylene or 1-ethynhyl-1-cyclohexanol gives the stable vinylidene [Os-(eta(5)-C5H5){=C=C(H)Ph}(CO)(PPr3i)]BF4 (5) or vinylvinylidene [Os(eta(5)-C5H5){=C=C(H)C=CH(CH2)(3)CH2}(CO)-(PPr3i)]BF4 (6), respectively.

  DOI：

  10.1021/om950620m