[Ru(C(=C(CN)2)C(=C(CN)2CN)(dppe)(Cp*)] | 879506-74-8

• 英文名称: [Ru(C(=C(CN)2)C(=C(CN)2CN)(dppe)(Cp*)]
• 英文别名: [Ru(C(=C(CN)2)C(=C(CN)2)CN)(1,2-bis(diphenylphosphino)ethane)(η5-C5Me5)]
• CAS: 879506-74-8
• 化学式: C₄₅H₃₉N₅P₂Ru
• 分子量: 812.856
• InChiKey: JWUVFFXGPGZAIL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  Ru(C≡C-C≡N)(dppe)Cp* 、 四氰基乙烯 以 二氯甲烷 为溶剂， 以63%的产率得到[Ru(C(=C(CN)2)C(=C(CN)2CN)(dppe)(Cp*)]
  参考文献：
  名称：

  The synthesis, structure, reactivity and electrochemical properties of ruthenium complexes featuring cyanoacetylide ligands

  摘要：

  The complex [Ru(C CC N)(dppe)Cp*] (1) is readily obtained (ca. 70%) from the sequential reaction of [Ru(C=CH2)(dppe)Cp*]PF6 with (BuLi)-Bu-n and phenyl cyanate. The complex behaves as a typical transition metal acetylide upon reaction with tetracyanoethene, affording a metallated pentacyanobutadiene. Complex I is a useful metalloligand, and its reactions with [W(thf)(CO)5], [RuCl(PPh3)(2)Cp], [RuCl(dppe)Cp*] or cis-[RuCl2(dppe)(2)] all afforded products featuring the M-C CC N-M' motif, for which ground state structures indicate a degree of polarisation. Electrochemical and spectroelectrochemical studies reveal moderate interactions between the metal centres in the 35-electron dications [{Cp*(dppe)Ru}(mu-C CC N){RuL2Cp'}](2+) Ru(PPh3)(2)CP, Ru(dppe)Cp*). (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.06.044