| 1429058-71-8

• CAS: 1429058-71-8
• 化学式: C₁₈H₁₆Br₂N₂NiS
• 分子量: 510.902
• InChiKey: LNTPANKBDNDSMD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-ethylquinoline-8-carboxylic acid 在 polyphosphoric acid 作用下， 以 二氯甲烷 为溶剂， 反应 18.0h， 生成
  参考文献：
  名称：

  Highly active 8-benzoxazolyl- or 8-benzothiazolyl-2-alkylquinolinylnickel(II) complexes for ethylene dimerization and vinyl polymerization of norbornene

  摘要：

  The series of nickel halide complexes LNiX2 (C1-C6, X = Cl; C7-C12, X = Br), where L represents one of 8-benzoxazolyl-2-alkylquinoline or 8-benzothiazolyl-2-alkylquinoline derivatives, have been prepared. The molecular structures of the representative complexes C1, C3, C6 and C11 were determined by single crystal X-ray diffraction. Upon activation with ethylaluminium sesquichloride (EASC), all nickel complex precatalysts exhibited good activities for ethylene dimerization. Furthermore, such nickel pre-catalysts, in the presence of methylaluminoxane (MAO), were capable of the vinyl polymerization norbornene. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.06.056